See the best alphabetical list of Countries and Capitals of South America.
| 1 | Argentina | Buenos Aires |
| 2 | Bolivia | Sucre |
| 3 | Brazil | Brasília |
| 4 | Chile | Santiago |
| 5 | Colombia | Bogotá |
| 6 | Ecuador | Quito |
| 7 | Falkland Islands | Stanley |
| 8 | French Guiana | Cayenne |
| 9 | Guyana | Georgetown |
| 10 | Paraguay | Asunción |
| 11 | Peru | Lima |
| 12 | South Georgia | King Edward Point |
| 13 | Suriname | Paramaribo |
| 14 | Uruguay | Montevideo |
| 15 | Venezuela | Caracas |
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